|
| Section4 = | Section3 = }} Cyclopropyl cyanide is the smallest carbon ring molecule with a cyanide group attached to it. It is mainly known by its involvement in experiments with microwave spectroscopy, rotational spectroscopy and photodissociation. In 1958, cyclopropyl cyanide was first studied for its rotational spectra, by Friend and Dailey. Additional experiment involving cyclopropyl cyanide was the determination of the molecule's dipole moment through spectroscopy experiments, by Carvalho in 1967. == Production == One method of synthesis of cyclopropyl cyanide is through reducing methy 3-cyanopropionate with lithium borodeuteride. This reduction yields an alcohol, which is further reacted triphenylphosphine and carbon tetrachloride. The product, 4-chlorobutyronitrile, is reacted with sodium iodide to replace the chloride with the iodide. Lastly, the molecule is turned into a cyclic molecule by reacting with sodium hydride. Another proposed method of synthesis involves reacting 4-chlorobutyronitrile with sodium amide. The sodium amide is produced by reacting solid sodium and liquid ammonia. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Cyclopropyl cyanide」の詳細全文を読む スポンサード リンク
|